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LLZTO Solid Electrolyte Tantalum Doped Lithium Lanthanum Zirconium Oxygen Li6.5La3Zr1.5Ta0.5O12

Categories Solid Electrolyte
Brand Name: XWELL
Model Number: LLZTO
Certification: CE
Place of Origin: CHINA
MOQ: 10pcs
Payment Terms: L/C,D/A,D/P,T/T,Western Union,MoneyGram
Supply Ability: 1 t/month
Delivery Time: 5-7 days
Packaging Details: Plastic package
Price: 1-1000USD/Negotiable
Model: LLZTO
Crystal Structure​: Cubic garnet (Ia-3d)
​​Density​: 95% theoretical (5.1 g/cm³)
Thickness Options​: 50–300 μm (customizable)
​​Ionic Conductivity​: 1.68×10 −3 S/cm (25°C)
​​Activation Energy​: 0.25–0.30 eV
Thermal Stability​: Up to 1000°C (melting point)
Storage: Argon glovebox (O₂/H₂O <0.1 ppm) to prevent Li₂CO₃ formation
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LLZTO Solid Electrolyte Tantalum Doped Lithium Lanthanum Zirconium Oxygen Li6.5La3Zr1.5Ta0.5O12

LLZTO Tantalum-doped Lithium Lanthanum Zirconium Oxygen Solid Electrolyte Sheet Li6.5La3Zr1.5Ta0.5O12 Battery Material

Material Overview​

LLZTO (Li₆.₅La₃Zr₁.₅Ta₀.₅O₁₂) is a cubic-phase garnet-type oxide solid electrolyte with superior ionic conductivity ( S/cm at 25°C) and exceptional electrochemical stability (0–5 V vs. Li⁺/Li). Its Ta doping stabilizes the cubic structure while suppressing lithium dendrite growth, making it ideal for lithium-metal batteries.

​Key Properties​

​Parameter​​Specification​
​Crystal Structure​Cubic garnet (Ia-3d)
​Density​>95% theoretical (5.1 g/cm³)
​Thickness Options​50–300 μm (customizable)
​Ionic Conductivity​ S/cm (25°C)
​Activation Energy​0.25–0.30 eV
​Thermal Stability​Up to 1000°C (melting point)

​Performance Highlights​

  1. ​Interface Engineering​

    • Forms stable SEI with Li metal (critical current density: 4.2 mA/cm²)
    • Low interfacial resistance (<10 Ω·cm² with Sn:SnF₂ coating)
  2. ​Mechanical Robustness​

    • Vickers hardness: 8–10 GPa
    • Withstands >300 MPa assembly pressure
  3. ​Battery Integration​

    • Compatible with NMC811 cathodes (181 mAh/g initial capacity)
    • Stable cycling >3000 cycles (0.1C rate)

​Applications​

  • ​All-Solid-State Lithium Batteries​​ (ASSLBs)
  • ​Lithium-Sulfur/Lithium-Air Batteries​
  • ​Hybrid Solid-Liquid Electrolyte Systems​

​Handling Notes​

  • ​Storage​​: Argon glovebox (O₂/H₂O <0.1 ppm) to prevent Li₂CO₃ formation
  • ​Processing​​: Cold-press at 300–500 MPa for pellet formation

Note: Custom formulations (e.g., Ga-doped LLZTO) and thicknesses available for research-scale orders.

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