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The productin capacity and original place of Ferrocene

Categories Fuel Oil Additives
Brand Name: JD
Model Number: JD-FETG-99
Certification: ISO 9001
Place of Origin: China
MOQ: one container
Payment Terms: T/T, L/C, T/T
Supply Ability: 500TONS per month
Delivery Time: 5 DAYS
Packaging Details: 25KG PP BAG
Price: $6700/tons
CAS NO: 102-54-5
UN NO: 1325
Class: 6.1
Package: 25kg kraft paper ,25kg cardboard drum
HS Code: 2931909090
Grade: Industry grade ,Battery grade ,Electronic grade
Purity: 98% ,99%
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The productin capacity and original place of Ferrocene

The main differences between ferrocene and N-methylaniline


Physical Properties:

FormulaC10H10FeCAS - NO102-54-5
U.N-NO1325Class4.1

Ferrocene (dicyclopentadienyliron) can be used: As a scaffold for chiral ligands in asymmetric catalysis.


Product details

Ferrocene is a crystal with orange needle-like structure that sublimates at temperatures higher than 100℃ and melts at 172.5-173℃. Its boiling point is 249℃. It is soluble in dilute nitric acid, concentrated sulfuric acid, benzene, petroleum and tetrahydrofuran and generates bluish fluorescence-containing deep red solution in dilute nitric acid and concentrated sulfuric acid. It is insoluble in water, 10% sodium hydroxide and hot concentrated hydrochloric acid, and it remains stable in air. Ferrocene has a strong property of UV absorbing and great thermostability, withstanding heating up to 470℃. It has a camphor-like scent and can be evaporated with water vapor. Ferrocene is neither dissolved nor decomposed in boiling solutions of these solvents.


Safety Information
Hazard CodesF,Xn,N
Risk Statements11-22-51/53-2017/11/22
Safety Statements61-22-24/25
RIDADRUN 1325 4.1/PG 2
OEBB
OELTWA: 10 mg/m3 (total)
WGK Germany2
RTECSLK0700000
Autoignition Temperature>150 °C
TSCAYes
HazardClass4.1
PackingGroupII
HS Code2931909090
Hazardous Substances Data102-54-5(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 1320 mg/kg LD50 dermal Rat > 3000 mg/kg

7.Chemical Parameters:

ItemIndex
Content:99.9% min99%min98%min.
Free Fe Content:0.01% max0.01%max0.02 %max.
Moisture:0.03% max0.1%max0.3 %max.
Insoluble matter in benzene0.15% max0.3%max0.5max

The main differences between ferrocene and N-methylaniline

1. Application Fields

Ferrocene


Fuel additive: used as a combustion rate catalyst for gasoline or rocket propellants, improving combustion efficiency and replacing toxic tetraethyl lead-5.

In the field of medicine, derivatives are used to treat anemia, tumors, and applied in photodynamic therapy.

Environmental Protection and Materials: Catalytic treatment of pollutants to improve the performance of polymer materials.

N-methylaniline


Pesticide synthesis: used for the production of insecticides and herbicides such as thiamethoxam and methyl herbicide.

Dyes and Chemicals: Used as dye intermediates (such as cationic brilliant red FG) and rubber additives.

Fuel improvement: increase gasoline octane rating, but with limited usage and control of residual 16.

2. Synthesis method

Ferrocene


Chemical synthesis method: Sodium cyclopentadienyl reacts with ferrous chloride to form ferrocene 3; Alternatively, electrolysis can be used to reduce cations through an iron plate electrode and combine them with cyclopentadiene.

Raw materials and conditions: Cyclopentadiene, iron powder or ferrous chloride are required, and the reaction often requires nitrogen protection and high temperature (such as 300 ℃).

N-methylaniline


Aniline methylation: Aniline reacts with methanol over copper zinc chromium catalyst or sulfuric acid catalyst to produce crude product, which is then distilled and purified.

Laboratory synthesis: Using dimethyl sulfate as a methylating agent, product 6 was separated through stepwise acid-base treatment.

3. Raw materials

Ferrocene:


The core raw materials are cyclopentadiene (C ₅ H ₆) and iron sources (such as iron powder and ferrous chloride) 37.

The auxiliary materials include solvents such as tetrahydrofuran and diethylamine.

N-Methylaniline:


The basic raw materials are aniline (C ₆ H ₅ NH ₂) and methylation reagents (such as methanol, dimethyl sulfate).

Catalysts commonly used include copper, zinc, chromium, or phosphorus trichloride.

4. Packaging method

Ferrocene:

Sealed moisture-proof packaging (such as aluminum foil bags or galvanized drums) is usually used to avoid contact with oxidants, and it should be labeled as "flammable solid" 57.

N-Methylaniline:

Commonly used dark glass bottles or plastic drums for packaging, should be stored away from light and labeled as "toxic" to prevent volatilization and oxidation


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